Abstract

07
F. J. Leeper and J. Staunton
"Rubrofusarin Biosynthesis in Fusarium culmorum: Incorporation of ¹³CH₃¹³CO₂H and CD₃¹³CO₂H into the Polyketide Naphthalene Nucleus"
J. Chem. Soc., Chem. Commun.,1982, 911-912. Full Text

The pattern of chain-folding in the linear polyketide precursor of the naphthalene nucleus of rubrofusarin has been determined by the standard technique using ¹³CH₃¹³CO₂H and by the b-shift technique using CD₃¹³CO₂H.

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