Terpene Synthase Database

Sorted by Compound number.

Click small structure to see it larger. Click column heading to sort by that column.
No. Structure Name C5 units Mechanism [explain] Cycles [explain] Organism Accession No. PDB Ref. Precursor of
1 Bornyl OPP, (+)- 2 c1-6,7-3,2-OPP [diagram] 2-[2.2.1]-2-OPP-1,7,7-Me common sage (Salvia officinalis) AAC26017, O81192, EC 5.5.1.8 1N23 7 (+)-camphor
ent-1 Bornyl OPP, (-)- 2 c1-6,7-3,2-OPP [diagram] 2-[2.2.1]-2-OPP-1,7,7-Me EC 5.5.1.22 (-)-camphor
2 Cineole, 1,8- 2 c1-6,7-w;H+2,3-O7 [diagram] 2-[2.2.2]-2-oxa-1,3,3-Me Streptomyces clavuligerus ATCC 27064, sage (Salvia officinalis, Salvia fruticosa ) WP_003952918, AAC26016, ABH07677, EC 4.2.3.108 2j5c 1, 7, 29
3 Linalool, (3R)- 2 c3-w 0-[8]-1,6-ene-3-ol-3,7-Me Artemisia annua, Streptomyces clavuligerus ATCC 27064 AAF13357, WP_003957954, EC 4.2.3.26 1
ent3 Linalool, (3S)- 2 c3-w 0-[8]-1,6-ene-3-ol-3,7-Me EC 4.2.3.25
4 Sabinene, (+)- 2 c1-6,7*H6-2,3-H3' [diagram] 2-[3.1.0]-2=CH2-5-iPr Sage (Salvia officinalis, Salvia pomifera ) AAC26018, ABH07678, EC 4.2.3.110 7
ent-4 Sabinene, (-)- 2 c1-6,7*H6-2,3-H3' [diagram] 2-[3.1.0]-2=CH2-5-iPr Arabidopsis thaliana P0DI76, P0DI77, EC 4.2.3.109 7
5 Aristolochene, (+)- 3 26; H+6,7-2,3*H2*7',7-H8 [diagram] 2-[4.4.0]-1-ene-4-C(=CH2)Me-6,7-Me Aspergillus terreus, Penicillium roqueforti Q9UR08 Q03471, EC 4.2.3.9 4KWD 1DI1 6, 62 PR-toxin, sporogen-AO1, phomenone
6 Bisabolene, (Z)-g- 3 c1-6,7-H6 [diagram] 1-[6]-1-ene-4=R-1-Me Arabidopsis thaliana NP_193066, NP_193064, EC 4.2.3.40 6
7 Trichodiene (bazzanene) 3 c1-6,7-H6+10,11-7,6*7',7*12,11-H11' (1-[6])-(1-[5])-3-ene-2'=CH2-1,4,1'-Me Trichothecium roseum; Fusarium sporotrichioides ABG74942, ABG74941, EC 4.2.3.6 1YYU 6 39 trichothecene
8 Pentalenene 3 1-11,10*H9-2,3*H2-6,7-H8 3-[6.3.0.04,8]-2-ene-2,6,6,9-Me Streptomyces exfoliatus UC5319 Q55012, EC 4.2.3.7 1PS1 1 pentalenolactone
9 Protoilludene,D6- 3 1-11,10*H9-2,3-6,7-H6 3-[6.3.0.02,5]-5-ene-2,6,10,10-Me Armillaria gallica AGR34199, EC 4.2.3.135
10 Sterpurene 3 1-11,10*H9-2,3-6,7*5,6*4,3-H2 3-[6.3.0.03,6]-1-ene-2,6,10,10-Me Stereum purpureum 9
11 Isozizaene, epi- 3 c1-6,7*H6-10,11-3,2*4,3*12,11-H10 3-[6.2.1.01,5]-5-ene-2,6,7,7-Me Streptomyces coelicolor A3(2) EC 4.2.3.37 3KB9 1 albaflavenone
12 Aristolochene, epi- 3 26; H+6,7-2,3*H2*7',7-H8 [diagram] 2-[4.4.0]-1-ene-4-C(=CH2)Me-6,7-Me Tobacco (Nicotiana tabacum) EC 4.2.3.61 1LZ9 Capsidiol
13 Bisabolol, (-)-a- 3 c1-6,7-w [diagram] 1-[6]-1-ene-4-R-1-Me Artemisia annua AFV40969 4FJQ, 4GAX 28
14 Limonene, 4S-(-)- 2 c1-6,7-H8 1-[6]-1-ene-4-C(C=CH2)Me-1-Me Mentha spicata (spearmint), Perilla frutescens, Abies grandis (grand fir) AAC37366, AAC37366, AAG31438, EC 4.2.3.16 2ONG, 2ONH 30
ent-14 Limonene, 4R-(+)- 2 c1-6,7-H8 1-[6]-1-ene-4-C(C=CH2)Me-1-Me Citrus sinensis, Agastache rugosa AAL17636, EC 4.2.3.20 5UV0, 5UV1
15 Terpinene, g- 2 c1-6,7*H6-H5 1-[6]-1,4-ene-4-iPr-1-Me Thymus vulgaris (thyme), Citrus limon (lemon) AAM53943, EC 4.2.3.114 5c05 31
16 Camphene, (+)- 2 c1-6,7-3,2*4,3-H3' [diagram] 2-[2.2.1]-2=CH2-3,3-Me ( ) EC 4.2.3.116
ent-16 Camphene, (-)- 2 c1-6,7-3,2*4,3-H3' [diagram] 2-[2.2.1]-2=CH2-3,3-Me Abies grandis (grand fir) AAB70707 EC 4.2.3.117
17 Fenchol, (-)-endo 2 c1-6,7-2,3*1,2-w [diagram] 2-[2.2.1]-2-ol-1,3,3-Me Lavander AGN72804, AGN72798, EC 4.2.3.10
18 Longifolene 3 c1-11,10*H1-6,7-3,2*4,3-H3' [diagram] 3-[5.4.0.02,9]-8=CH2-3,3,7-Me Picea abies (spruce), Pinus roxburghii Sarg. AAS47695, EC 4.2.3.58
19 Longiborneol 3 c1-11,10*H1-6,7-3,2-w 3-[5.4.0.02,9]-8-ol-2,6,6,9-Me Fusarium graminearum ACY69978 6 culmorin
20 Acorenol, a- 3 c1-6,7*H6-10,11-w 2-spiro[4.5]-7-ene-1-C(OH)Me2-4,8-Me Fusarium fujikuroi 751349791 6
21 Koraiol 3 1-11,10-2,3-6,7-w 3-[7.2.0.02,5]-8-ol-1,4,4,8-Me Fusarium fujikuroi ACY69978 6
22 Bisabolene, a- 3 c1-6,7-H8 [diagram] 1-[6]-1-ene-4-R-1-Me Abies grandis (grand fir) AAC24192, EC 4.2.3.38 3SDQ 25
23 Presilphiperfola-8b-ol 3 1-11,10-2,3*1,2-6,7*H2-w [diagram] 3-[6.2.1.04,11]-11-ol-1,3,3,7-Me Botrytis cinerea Q6WP50, EC 4.2.3.74 6 8 botrydial
24 Vetispiradiene (premnaspirodiene) 3 26; H+6,7-2,3*H2*8,7-H6 [diagram] 2-spiro[4.5]-6-ene-2-C(=CH2)Me-6,10-Me Hyoscyamus muticus Q39980 , EC 4.2.3.21 5JO7
25 Cedrene (funebrene), (+)-a- 3 c1-6,7*H6-10,11-2,3-H4 3-[5.3.1.01,5]-8-ene-2,6,6,8-Me
26 Germacrene A, (+)- 3 1-10,11-H12 1-[10]-1,5-ene-8-C(=CH2)Me-1,5-Me Nostoc sp. PCC7120; Anabaena variabilis ATCC 29413; Chitinophaga pinensis DSM 2588 WP_010998816; WP_011318775, WP_012789469, EC 4.2.3.23 1
27 Germacradien-6-ol, (+)-(1(10)E,4E,6S,7R)- 3 1-10,11*H1-w 1-[10]-1-ol-2,6-ene-10-iPr-3,7-Me Streptomyces pratensis ATCC 33331 ADW03055 1
28 Germacradien-4-ol, (-)- 3 1-10,11*H1,3-w 1-[10]-2,7-ene-1-ol-4-iPr-1,7-Me Streptomyces citricolor NBRC 13005; Streptomyces lactacystinaeus OM-6519 AB621338; BAP82213 5i1u 1, 61
29 Bicyclogermacrene 3 1-10,11-H1 [diagram] 2-[8.1.0]-2,6-ene-3,7-Me Oregano (Origanum vulgare L.), Lippia dulcis E2E2N7, J7LMP2, EC 4.2.3.100 1
30 Germacrene D, (-)- 3 1-10,11*H1-H3' [diagram] 1-[10]-1,5-ene-8-C(=CH2)Me-1,5-Me grapevine (Vitis vinifera) Q6Q3H3 , EC 4.2.3.75 6
ent-30 Germacrene D, (+)- 3 1-10,11*H1-H3' [diagram] 1-[10]-1,5-ene-8-C(=CH2)Me-1,5-Me grapevine (Vitis vinifera), Solidago canadensis NP_00126821, EC 4.2.3.77 6
31 Zonarene, epi- 3 c1-10,11*H1-6,7*H1-H10 2-[4.4.0]-4,6-ene-7-iPr-4,10-Me Jack-O-Lantern mushroom (Omphalotus olearius) Omp5a 6
32 Cubebol 3 c1-10,11*H1-6,7*H6-H2 [diagram] 3-[4.4.0.01,5]-7-iPr-4,10-Me Coprinus cinereus Cop4, EC 4.2.3.91 6
33 Cedrol, 8-epi 3 c1-6,7*H6-10,11-2,3-w 3-[5.3.1.01,5]-8-ol-2,6,6,8-Me Artemisia annua AAF80333, EC 4.2.3.39
34 Avermitilol 3 29; H+3,2-7,6-w [diagram] 3-[5.4.0.02,4]-8-ol-3,3,7,11-Me Streptomyces avermitilis MA-4680 WP_010981512 EC 4.2.3.96 1
35 Casbene 4 1-14,15-H1 2-[12.1.0]-2,5,10-ene-3,7,11,15,15-Me EC 4.2.3.8
36 Viridiflorol 3 29; H+3,2-6,7-w 3-[6.3.0.02,4]-7-ol-3,3,7,11-Me
37 Sabinene hydrate 2 c1-6,7*H6-2,3-w 2-[3.1.0]-2-ol-5-iPr-2-Me ( ) EC 4.2.3.11
38 Myrcene 2 1-H3' 0-[8]-1,6-ene-3=CH2 Abies grandis (grand fir) AAB71084, EC 4.2.3.15
39 Santalene, (+)-a- 3 c1-6,7-3,2-H4 [diagram] 3-[2.2.1.02,6]-3-R-2,3-Me EC 4.2.3.50
40 Phellandrene, (-)-(4S)-b- 2 c1-6,7*H1-H3' 1-[6]-1-ene-3=CH2-6-iPr Abies grandis (grand fir) AAF61453, EC 4.2.3.51 EC 4.2.3.52
41 Bisabolene, (S)-b- c1-6,7-H7' [diagram] 1-[6]-1-ene-4-R-1-Me EC 4.2.3.55
42 Cadinene, (+)-g- 3 c1-10,11*H1-6,7-H10 2-[4.4.0]-7-ene-2=CH2-5-iPr-8-Me Jack-O-Lantern mushroom (Omphalotus olearius), Chitinophaga pinensis DSM 2588 WP_012792334, Omp5a/b, EC 4.2.3.92
ent-42 Cadinene, (-)-g- 3 c1-10,11*H1-6,7-H10 2-[4.4.0]-7-ene-2=CH2-5-iPr-8-Me Heteroscyphus planus EC 4.2.3.62
43 Cadinene, (-)-d- 3 c1-10,11*H1-6,7-H6 [diagram] 2-[4.4.0]-1,7-ene-5-iPr-2,8-Me Streptomyces clavuligerus ATCC 27074 WP_003954606, EC 4.2.3.97 1
ent-43 Cadinene, (+)-d- 3 c1-10,11*H1-6,7-H6 [diagram] 2-[4.4.0]-1,7-ene-5-iPr-2,8-Me Cotton (Gossypium arboreum) EC 4.2.3.13 3g4d 32 gossypol
44 Muurolol, (+)-T- 3 c1-10,11*H1-6,7-w [diagram] 2-[4.4.0]-7-ene-2-ol-5-iPr-2,8-Me Streptomyces clavuligerus ATCC 27074; Roseiflexus castenholzii DSM 13941; Roseiflexus sp. RS-1 WP_003956090, WP_012119179, WP_011958209, EC 4.2.3.98 1
45 Bergamotene, (+)-endo-b- 3 c1-6,7-2,3-H3' 2-[3.1.1]-2=CH2-6-R-6-Me EC 4.2.3.53
46 Bergamotene, (-)-endo-a- 3 c1-6,7-2,3-H4 2-[3.1.1]-2-ene-6-R-2,6-Me wild tomato (Solanum habrochaites) EC 4.2.3.54
47 Humulene, g- 3 1-11-10*H1-H3' [diagram] 1-[11]-1,6-ene-3=CH2-7,11,11-Me Abies grandis (grand fir) AAC05728, EC 4.2.3.56
48 Bisabolene, (E)-g- 3 c1-6,7-H6 [diagram] 1-[6]-1-ene-4=R-1-Me EC 4.2.3.59
49 Germacrene C 3 1-10,11*H10-H1 1-[10]-1,3,7-ene-1-iPr-4,8-Me EC 4.2.3.60
50 Cubenene, (+)- c1-10,11*H1-6,7*H6-H5 2-[4.4.0]-1,4-ene-7-iPr-4,10-Me EC 4.2.3.63
51 Cubenol, (+)-epi- 3 c1-10,11*H1-6,7*H6-w 2-[4.4.0]-3-ene-1-ol-7-iPr-4,10-Me Streptomyces griseus NBRC 13350 WP_012381690, EC 4.2.3.64 1
52 Bisabolol, (-)-epi-a- 3 c1-6,7-w [diagram] 1-[6]-3-ene-1-R-4-Me Streptomyces citricolor NBRC 13005 AB621339 1
ent-52 Bisabolol, (+)-epi-a- 3 c1-6,7-w [diagram] 1-[6]-3-ene-1-R-4-Me Phyla dulcis (Aztec sweet herb) J7LH11, EC 4.2.3.138 1
53 Zingiberene 3 c1-6,7*H1-H4 (or *H5-H4?) [diagram] 1-[6]-1,3-ene-5-R-2-Me EC 4.2.3.65
54 Caryophyllene, (-)-(E)-b- 3 1-11,10-2,3-H3' [diagram] 2-[7.2.0]-4-ene-8=CH2-4,11,11-Me clove oil, rosemary, hops, Saccharothrix espanaensis DSM 44229 WP_041318180 EC 4.2.3.57 1
ent-54 Caryophyllene, (+)-(E)-b- 3 1-11,10-2,3-H3' [diagram] 2-[7.2.0]-4-ene-8=CH2-4,11,11-Me Streptomyces griseus EC 4.2.3.89
55 Caryolan-1-ol, (+)- 3 ent-54; H+6,7-3',3-w [diagram] 3-[6.3.1.02,5]-1-ol-4,4,8-Me Streptomyces griseus NBRC 13350 EC 4.2.1.138 1
56 Hedycaryol, (2E,6E)- 3 1-10,11-w 1-[10]-1,5-ene-8-C(OH)Me2-1,5-Me Saccharopolyspora spinosa NRRL 18395 WP_010314578 1
57 Hedycaryol, (2Z,6E)- 3 c1-10,11-w 1-[10]-1,5-ene-8-C(OH)Me2-1,5-Me Kitasatospora setae KM-6054 WP_014133196 4MC3 1, 47
58 Allohedycaryol, (+)- 3 56; H+3,2-H1 (?) Mycobacterium marinum M WP_012394883 1
59 Selinene, 5-epi-a- 3 26; H+6,7-2,3-H4 2-[4.4.0]-1-ene-9-C(=CH2)Me-2,6-Me Nostoc punctiforme PCC73102 WP_012410187, EC 4.2.1.90 1
60 Selina-4(15),7(11)-diene 3 1-10-H10; H+6,7-2,3-H9 2-[4.4.0]-2=CH2-9=CMe2-6-Me Streptomyces pristinaespiralis ATCC 25486 WP_005317515 4OKZ 1, 27
61 Selina-3,7(11)-diene 3 1-10,11-H10; H+6,7-2,3-H4 2-[4.4.0]-2-ene-9=CMe2-6-Me Streptomyces tsukubaensis NRRL 18488; Streptomyces sp. SK 1894 WP_006348376; BAP82223 1
62 Farnesene, a- 3 1-H4 0-[12]-1,3,6,10-ene-3,7,11-Me EC 4.2.3.46
63 Farnesene, b- 3 1-H3' 0-[12]-1,6,10-ene-3=CH2-7,11-Me EC 4.2.3.47
64 Nerolidol, (3S,6E)- 3 c3-w 0-[12]-1,6,10-ene-3-ol EC 4.2.3.48
65 Nerolidol, (3R,6E)- 3 c3-w 0-[12]-1,6,10-ene-3-ol EC 4.2.3.49
66 Sandaracopimara-8(14),15-diene, ent- 4 ent-107; 3-7',7-H7' 3-[8.4.0.02,7]-6-ene-5-vinyl-1,5,11,11-Me rice EC 4.2.3.29 35
67 Cassa-12,15-diene, ent- 4 ent-107; 3-7',7*H7'*3',3-H4 3-[8.4.0.02,7]-4-ene-5-vinyl-1,6,11,11-Me rice EC 4.2.3.28 phytocassanes
68 Corvol ether A 3 c1-10,11*H1,3-w; H+2,3-6,7*H6*H1*H10-O3 3-[6.2.1.05,10]-11-oxa-1-iPr-4,8-Me Kitasatospora setae KM-6054 WP_014134444 1, 60
69 Corvol ether B 3 c1-10,11*H1-w; H+2,3-6,7*H6*H1*9,10-O3 3-[5.2.2.04,9]-11-oxa-10-iPr-3,7-Me Kitasatospora setae KM-6054 WP_014134444 1, 60
70 Elisabethatriene 4 (c?)1-10,11*H1-6,7*H6*H1-H3' 2-[4.4.0]-ene-3=CH2-10-R-7-Me Pseudopterogorgia elisabethae EC 4.2.3.41 Pseudopterosins
71 Fusicocca-2,10(14)-diene 4 1-11,10-14,15*H14-H10+2,3-H2+6,7*H6-2,3-H2 [diagram] 3-[9.3.0.03,7]-3,11-ene-12-iPr-4,8,15-Me Phomopsis amygdali 5ER8_A , EC 4.2.3.43 5ERM, 5ER8 21-23 Fusicoccin A
72 Eremophilene, (+)- 3 26; H+6,7-2,3*H2*7',7-H6 2-[4.4.0]-2-ene-8-C(=CH2)Me-5,6-Me Sorangium cellulosum so ce56 WP_012241161 1
73 Isoafricanol 3 1-11,10*H9-7,6-2,3*H2-w 3-[6.3.0.02,4]-8-ol-2,6,6,9-Me Streptomyces violaceusniger Tu 4113 WP_043239846 1,71
74 Selinene, b- 3 26; H+6,7-2,3-H3' 2-[4.4.0]-2=CH2-9-C(=CH2)Me-6-Me EC 4.2.3.66
75 Amorphene, a- 3 c1-6,7*H1-10,11*H7-H8 2-[4.4.0]-2,7-ene--5-iPr-2,8-Me Streptomyces viridochromogenes DSM 40736 WP_039931950 1, 59
76 Eudesmol, 7-epi-a- 3 56; H+6,7-2,3-H4 [diagram] 2-[4.4.0]-2-ene-9-C(OH)Me2-2,6-Me Streptomyces viridochromogenes DSM 40736; Zingiber zerumbet Smith WP_003994861; ZSS2 1 , 3
77 Amorpha-4,11-diene 3 c1-6,7*H1-10,11-H12 2-[4.4.0]-2-ene-10-C(=CH2)Me-3,7-Me Artemisia annua CAB94691, EC 4.2.3.24 artemisinin
78 Cubebol, epi- 3 c1-10,11*H1-6,7*H6-2,3-w 3-[4.4.0.01,5]-4-ol-7-iPr-4,10-Me Streptosporangium roseum DSM 43021 WP_012893303 1
79 African-2-ene 3 1-11,10*H9-7,6-2,3-H2 3-[6.3.0.02,4]-8-ene-2,6,6,9-Me Streptomyces clavuligerus ATCC 27074 WP_003963391 1
80 Intermedeol 3 26; H+6,7-2,3-w 2-[4.4.0]-2-ol-9-C(=CH2)Me-2,6-Me Streptomyces clavuligerus ATCC 27074 WP_003955204 1
81 Selinene, a- 3 26; H+6,7-2,3-H4 2-[4.4.0]-2-ene-9-C(=CH2)Me-2,6-Me Herpetosiphon aurantiacus DSM 785 WP_012190525 1
82 Dauca-8,11-diene, (+)- 3 c1-7,6-10,11-H12 2-[5.3.0]-3-ene-8-C(=CH2)Me-1,4-Me Streptomyces venezuelae ATCC 10712 CCA53839 1
83 Phomopsene 4 1-11,10-14,15*13,14*11,10-2,3*H2-6,7-H6 4-[7.6.0.01,5.010,14]-5-ene-2,6,11,11,14-Me Phomopsis amygdali N2 20, 43
84 Bicyclosesqui-phellandrene 3 c1-10,11*H1-6,7*H1-H3' 2-[4.4.0]-1-ene-3=CH2-10-iPr-7-Me Sorangium cellulosum so ce56 WP_012238985 1
85 Isohirsut-1-ene, (-)- 3 1-11,10*H9-2,3-6,7*5,6*2,3*H2-H1 3-[6.3.0.02,6]-2-ene-4,4,8,11-Me Streptomyces clavuligerus ATCC 27074 EFG04889 1, 46
86 Isohirsut-4-ene, (-)- 3 1-11,10*H9-2,3-6,7*5,6*2,3-H4 3-[6.3.0.02,6]-10-ene-4,4,8,11-Me Streptomyces lactacystinaeus OM-6519 BAP82216 1, 46
87 Hirsutene 3 1-11,10*H9-2,3-7,6*8,7*2,3-H3' 3-[6.3.0.02,6]-3=CH2-2,10,10-Me Stereum hirsutum
88 Cyclooctat-9-en-7-ol 4 1-11,10-14,15*H8,6-2,3 *H6*H10-8,7*9,10*8,7-w 3-[9.3.0.03,7]-10-ene-8-ol-12-iPr-1,4,8-Me Streptomyces melanosporofaciens MI614-43F2 BAI44338, EC 4.2.3.146 4OMG 1, 2
89 Taxa-4,11-diene 4 1-14,15-10,11-H10+6,7-2,3-H4 [diagram] 3-[9.3.1.03,8]-4,11-ene-4,8,12,16,16-Me Pacific yew (Taxus brevifolia) EC 4.2.3.17 3P5R 12
90 Spiroviolene 4 1-11,10-14,15*13,14*11,10-2,3 -6,7*3,6*7',7*2,3*H2-H1 spiro-(1-[5])-1,4'-(3-[6.3.0.03,7])-2-ene-1,9,9,2',5'-Me Streptomyces violens NRRL ISP-5597 WP_051831532 10
91 Nephthenol, (R)- 4 1-14,15-w 1-[14]-1,5,9-ene-13-C(OH)Me2-2,6,10-Me Streptomyces sp. SANK 60404 DtcycA, EC 4.2.3.149 1
92 (E,E,E)-2,2,5,9,13-Pentamethylcyclopentadeca -4,8,12-trien-1-ol 4 1-15,14-w 1-[15]-1-ol-4,8,12-ene-2,2,5,9,13-Me Streptomyces sp. SANK 60404 DtcycB 1, 36
93 Hydropyrene 4 1-10,11*H1-14,15-H16; H+6,7-2,3-16,15-H15' 4-[9.3.2.08,16.011,15]-2=CH2-4,8,12-Me Streptomyces clavuligerus ATCC 27074 WP_003963279 1, 46
94 Hydropyrenol 4 1-10,11*H1-14,15-H16; H+6,7-2,3-16,15-w 4-[9.3.2.08,16.011,15]-2-ol-2,4,8,12-Me Streptomyces clavuligerus ATCC 27074 WP_003963279 1, 46
95 Isoelisabethatriene B 4 c1-10,11*H1-6,7-H6 2-[4.4.0]-1,7-ene-5-R-2,8-Me Streptomyces clavuligerus ATCC 27074 WP_003963279 1, 46
96 Clavulatriene A 4 1-10,11-H14; H+6,7-2,3-H2 2-[4.4.0]-1-ene-9-R-2,6-Me Streptomyces clavuligerus ATCC 27074 EFG04655 1, 46
97 Clavulatriene B 4 1-10,11-H10; H+6,7-2,3*H2-H1 2-[4.4.0]-1-ene-3=R-6,10-Me Streptomyces clavuligerus ATCC 27074 EFG04655 1, 46
98 Prenylgermacrene B 4 1-10,11-H10 1-[10]-1,5-ene-8=R-1,5-Me Streptomyces clavuligerus ATCC 27074 EFG04655 1, 46
99 Tsukubadiene 4 1-11,10-14,15*13,14*11,10 *H9-7,6-2,3*H2*H6*8,9*7,6*H2-H1 3-[10.3.0.03,7]-1,9-ene-3,6,6,10,15-Me Streptomyces tsukubaensis NRRL 18488 EIF90392 1, 10, 46
100 Odyverdiene A 4 1-10,11*H1-14,15-H16; H+3,2-6,7-H7' 3-[8.4.0.03,6]-7=CH2-14-C(=CH2)Me-3,11-Me Streptomyces sp. ND90 BAP82229 1, 46
101 Odyverdiene B 4 1-10,11*H1-14,15-H16; H+2,3-6,7-H7' 3-[8.4.0.02,6]-7=CH2-14-C(=CH2)Me-3,11-Me Streptomyces sp. ND90 BAP82229 1, 46
102 Cyclooctat-7(8),10(14)-diene 4 1-11-14*H8,6-2*H6*H10-H14 3-[9.3.0.03,7]-8,11-ene-12-iPr-1,4,8-Me Streptomyces lactacystinaeus OM-6519 BAP82203 1
103 Cembrene 4 1-14*H1-H4 1-[14]-1,3,6,10-ene-14-iPr-3,7,11-Me Rubrobacter xylanophilus DSM 9941 WP_041328593 1
104 Obscuronatin 4 1-10*H1,3-w 1-[10]-2,7-ene-1-ol-4-R-1,7-Me Herpetosiphon aurantiacus DSM 785 WP_012190524 1
105 Terpentedienyl OPP 4 H+14,15-10,11-6,7*H6 *11',11*H10*16,15-H14 2-[4.4.0]-2-ene-7-R-1,2,7,8-Me Streptomyces griseolosporus MF730-N6 type II cyclase Q9AJE4, EC 5.5.1.15 1, 5 terpentecin
106 Terpentetriene 4 105; 1-H3' 2-[4.4.0]-2-ene-7-R-1,2,7,8-Me Streptomyces griseolosporus MF730-N6 type I cyclase Q9AJE3, EC 4.2.3.36 1, 5
107 Copalyl OPP 4 H+14,15-10,11-6,7-H7' 2-[4.4.0]-3=CH2-2-R-1,7,7-Me Salinispora arenicola type II cyclase EC 5.5.1.12 1
ent-107 Copalyl OPP, ent- 4 H+14,15-10,11-6,7-H7' 2-[4.4.0]-3=CH2-2-R-1,7,7-Me Streptomyces sp. KO-3988; Bradyrhizobium japonicum USDA 110; Streptomyces platensis MA7327 and MA7339; Arabidopsis thaliana type II cyclase PtmT2, EC 5.5.1.13 3PYA, 3PYB 1, 13 terpentecin
108 Pimara-9(11),15-diene, ent-(-)- 4 ent-107; 3-7',7*H6-H5 3-[8.4.0.02,7]-2-ene-5-vinyl-1,5,11,11-Me Streptomyces sp. KO-3988 type I cyclase EC 4.2.3.31 1
109 Kaurene, ent- 4 ent-107; 3-7',7*4,3-H3' [diagram] 4-[11.2.1.01,10,04,9]-14=CH2-5,5,9-Me Bradyrhizobium japonicum USDA 110; Streptomyces platensis MA7327, Fusarium fujikuroi type I cyclase; PtmT3, EC 4.2.3.19 4XLY 4 gibberellins, platensimycin
110 Atiserene, ent- 4 ent-107; 3-7',7*H4*2,3-H3' 4-[10.2.2.01,10.04,9]-13=CH2-5,5,9-Me Streptomyces platensis MA7327 PtnT1 4 platencin
111 Isopimara-8(14),15-diene 4 107; 3-7',7-H7' [diagram] 3-[8.4.0.02,7]-6-ene-5-vinyl-1,5,11,11-Me
112 Abieta-7,13-diene 4 111; H+1,2*3',3-H8 3-[8.4.0.02,7]-5,7-ene-5-iPr-1,11,11-Me Abies grandis Q38710.1 , EC 4.2.3.18 3s9v 11
113 Tuberculosinyl OPP (halima-5,13-dien-15-yl-OPP) 4 H+14,15-10,11-6,7*H6*11',11*H10-H9 2-[4.4.0]-3=CH2-2-R-1,7,7-Me Mycobacterium tuberculosis Rv3377c, EC 5.5.1.16 1 1-tuberculos-inyladenosine
114 Aphidicolan-16b-ol 4 115; 3-7',7*H6-1,2*4,3-w 4-[10.3.1.02,7.01,10]-13-ol-2,6,6,13-Me Phoma betae PS-13 Q96WT2 (bifunctional), EC 4.2.3.42 16 aphidicolin
115 Copalyl OPP, syn- 4 H+14,15-10,11-6,7-H7' 2-[4.4.0]-3=CH2-2-R-1,7,7-Me Phoma betae PS-13 Q96WT2 16 aphidicolin
116 Mutilin, dideoxy-, premutilin 4 H+14,15-10,11-6,7*H6 *11',11*H10*14,15-H16; 3-16,15*H5-w (or 15*H16-w ?) 3-[5.4.3.01,8]-6(or 3)-ol-4-vinyl-2,4,7,14-Me Clitopilus passeckerianus 17-19, 72 Pleuromutilin
117 Kolavenyl OPP 4 H+14,15-10,11-6,7*H6 *11',11*H10*16,15-H14 2-[4.4.0]-2-ene-7-R-1,2,7,8-Me Herpetosiphon aurantiacus type II cyclase 1
118 Verticillene, E,E- 4 1-14,15-10,11-H10 -[9.3.1]-3,7,11-ene-4,8,12,16,16-Me
119 Isopimara-8,15-diene, ent- 4 ent-107; 3-7',7-H6 3-[8.4.0.02,7]-2(7)-ene-5-vinyl-1,5,11,11-Me Salinispora arenicola type I cyclase 1
120 Pimara-8,15-diene, ent- 4 ent-107; 3-7',7-H6 3-[8.4.0.02,7]-2(7)-ene-5-vinyl-1,5,11,11-Me Aspergillus nidulans CBF85186 (bifunctional type I+II cyclase) 14
121 Phyllocladan-16a-ol 4 ent-107; 3-7',7*4,3-w 4-[11.2.1.01,10,04,9]-14-ol-5,5,9,14-Me Phomopsis amygdali 186704304 (bifunctional type I+II cyclase), EC 4.2.3.45 15
122 Isolepidozene 3 1-10,11-H1 2-[8.1.0]-2,6-ene-3,7-Me 1
123 Germacradien-11-ol, (1(10)E,5E)- 3 122; H+3,2*1,11-w 1-[10]-1,6-ene-10-C(OH)Me2-3,7-Me EC 4.2.3.22 5dz2 1, 26
124 Octalin 3 123; H+6,7-2,1*10,11 2-[4.4.0]-2-ene-6,10-Me 1
125 Geosmin 3 124; H+10,1*H2-w 2-[4.4.0]-1-ol-2,6-Me Nostoc punctiforme PCC73102; Streptomyces coelicolor A3(2) WP_012409287; WP_011030632 Bifunctional 5dz2 (N-term) 1, 26
126 Methylisoborneol, 2- 2 2-MeGPP; c1-6,7-3,2-w [diagram] 2-[2.2.1]-2-ol-1,2,7,7-Me Pseudoanabaena limnetica Castaic Lake; Streptomyces coelicolor A3(2) HQ630883, WP_011031839 , EC 4.2.3.118 3V1V 1
127 Methylenebornane, 2- 2 2MeGPP; c1-6,7-3,2-H2' 2-[2.2.1]-2=CH2-1,7,7-Me Pseudomonas fluorescens PfO-1 WP_011333305, EC 4.2.3.118 1
128 Squalene 3+3 1-2,3-H1; 1*1,3*2,1-(H-NADP) 0-[24]-2,6,10,14,18,22-ene-2,6,10,15,19,23-Me P37268, EC 2.5.1.21 3wei
129 Squalene, 2,3-oxido 6
130 Hopene 6 128; H+3,2-7,6-11,10-15,14-19,18-22,23-H24 5-[11.8.0.02,10.05,9.014.19]-6-C(=CH2)Me-1,2,9,14,18,18-Me Alicyclobacillus acidocaldarius WP_014465455, EC 5.4.99.17 1SQC 24
131 Lanosterol 6 129; H+O2,2-7,6-11,10-15,14-18,19*H18*H14*15',15*10',10-H11 [diagram] 4-{8.7.0.02,7.011,15]-5-ol-1(10)-ene-14-R-2,6,6,11,15-Me EC 5.4.99.7 1w6k 33
132 Cycloartenol 6 129; H+O2,2-7,6-11,10-15,14-18,19*H18*H14*15',15*10',10*H11-H6' [diagram] 5-[9.7.0.01,3.03,8.012,16]-6-ol-15-R-7,7,12,16-Me EC 5.4.99.8
133 Isoprene 1 1-H4 0-[4]-1,3-ene-3-Me Grey Poplar EC 4.2.3.27 3n0g
134 Pimara-8(14),15-diene, ent- 4 ent-107; 3-7',7-H7' 3-[8.4.0.02,7]-6-ene-5-vinyl-1,5,11,11-Me EC 4.2.3.30
135 Abieta-8(14),12-diene (Levopimaradiene) 4 111; H+1,2*3',3-H4 3-[8.4.0.02,7]-4,6-ene-5-iPr-1,11,11-Me Ginkgo biloba EC 4.2.3.32 ginkgolides
136 Stemar-13-ene 4 115; 3-7',7*H6-1,2*4,3-H7' [diagram] 4-[11.2.1.01,10.02,7]-11-ene-2,6,6,12-Me rice EC 4.2.3.33 oryzalexin
137 Stemod-13(17)-ene 4 115; 3-7',7*H6-1,2*7',3-H3' [diagram] 4-[10.3.1.01,10.02,7]-13=CH2-2,6,6-Me EC 4.2.3.34 oryzalexin
138 Pimara-7,15-diene, syn 4 115; 3-7',7-H8 4-[10.3.1.01,10.02,7]-13=CH2-2,6,6-Me rice (Oryza sativa) EC 4.2.3.35 34 momilactones
139 Isopimara-7,15-diene 4 107; 3-7',7-H8 [diagram] 3-[8.4.0.02,7]-2(7)-ene-5-vinyl-1,5,11,11-Me type I cyclase EC 4.2.3.44
140 Silphiperfol-6-ene 3 1-11,10-2,3*1,2-6*9,10*12,11-H10 3-[6.3.0.01,5]-2-ene-2,3,5,9-Me Hypoxylon rickii 37
141 Muurola-4(14),5-diene, cis 3 c1-10,11*H1-6,7*H6*H1-H3' [diagram] 2-[4.4.0]-1-ene-3=CH2-10-iPr-7-Me Mentha x piperita Q5W283, EC 4.2.3.67
142 Eudesmol, b- 3 56; H+6,7-2,3-H3' [diagram] 2-[4.4.0]-2=CH2-9-C(OH)Me2-6-Me Zingiber zerumbet (bitter ginger) B1B1U4, EC 4.2.3.68
143 Barbatene, (+)-a- 3 c1-6,7-H6+10,11-7,6*7',7*12,11-2,3-H4 [diagram] 3-[5.3.1.02,6]-8-ene-1,2,6,8-Me Arabidopsis thaliana Q4KSH9 EC 4.2.3.69 39
144 Patchoulol, (-) 3 1-10,11-7,6-2,3*H6*11,7*2,6-w [diagram] 3-[5.3.1.03,8]-7-ol-4,8,12,12-Me Pogostemon cablin ALQ43502 EC 4.2.3.70 38
145 Germacrene B 1-10,11-H10 1-[10]-1,5-ene-9=CMe2-2,6-Me Solanum habrochaites Q9FQ27, EC 4.2.3.71
146 Gurjunene, (-)-a- 3 29; H+7,6-2,3-H2 [diagram] 3-[6.3.0.02,4]-1(11)-ene-3,3,7,11-Me Solidago canadensis EC 4.2.3.72
147 Valencene, (+)- 3 26; H+6,7-2,3*H2*7',7-H6 [diagram] 2-[4.4.0]-1-ene-8-C(CH2)Me-5,6-Me Vitis vinifera NP_001268215 EC 4.2.3.73
148 Selinene, (+)-d- 3 ; H+6,7-2,3-H2 [diagram] 2-[4.4.0]-1(10),2-ene-3-iPr-6,10-Me Fir (Abies grandis) O64404, EC 4.2.3.76
149 Chamigrene, (+)-b- 3 c1-6,7-H6+10,11-6,7-H7' spiro[5.5]-2-ene-7=CH2-3,11,11-Me Arabidopsis thaliana EC 4.2.3.78 39
150 Thujopsene, (+)- 3 c1-6,7-H6+10,11-6,7*5,6-2,3-H4 3-[5.4.0.01,3]-4-ene-4,7,11,11-Me Thujopsis dolabrata, Juniperus cedrus EC 4.2.3.79 39
151 Longipinene, (+)-a- 3 c1-11,10*H1-6,7-2,3*4,3-H4 [diagram] 3-[5.4.0.02,8]-9-ene-2,6,6,9-Me Norway spruce, (Picea abies), Pinus sylvestris Q675L0, EC 4.2.3.80
152 Bergamotene, (-)-exo-a- 3 c1-6,7-2,3-H4 [diagram] 2-[3.1.1]-2-ene-6-R-2,6-Me Lavender (Lavandula angustifolia) Q2XSC4, EC 4.2.3.81
153 Santalene, (-)-b- 3 c1-6,7-3,2*4,3-H3' [diagram] 2-[2.2.1]-2=CH2-3-R-3-Me EC 4.2.3.83
154 Eudesmol, 10-epi-g- 3 56; H+6,7-2,3-H2 [diagram] 2-[4.4.0]-1-ene-9-C(OH)Me2-2,6-Me EC 4.2.3.84
155 Eudesmol, a- 3 56; H+6,7-2,3-H4 [diagram] 2-[4.4.0]-2-ene-9-C(OH)Me2-2,6-Me EC 4.2.3.85
156 Selinene, 7-epi-a- 3 ent-26; H+6,7-2,3-H4 [diagram] 2-[4.4.0]-1-ene-9-C(=CH2)Me-2,6-Me Grapevine (Vitis vinifera) EC 4.2.3.86
157 Guaiene, a- 3 26; H+3,2-6,7*H6-H2 [diagram] 2-[5.3.0]-1(7)-ene-3-C(=CH2)Me-6,10-Me Pogostemon cablin EC 4.2.3.87
158 Guaiene, d- (a-bulnesnene) 3 26; H+3,2-6,7-H6 [diagram] 2-[5.3.0]-1-ene-5-C(=CH2)Me-2,8-Me Aquilaria crassna EC 4.2.3.93
159 Viridiflorene 3 29; H+3,2-6,7-H6 [diagram] 3-[6.3.0.02,4]-7-ene-3,3,7,11-Me EC 4.2.3.88
160 Curcumene, g- 3 c1-6,7*H6-H1 [diagram] 1-[6]-1,3-ene-1-R-4-Me Pogostemon cablin Q49SP7, EC 4.2.3.94
161 Cuparene, (-)-a- 3 c1-6,7-H6+10,11-7,6-H1 (1-[6])-(1-[5])-1,3-ene-4,1',2',2'-Me , EC 4.2.3.95 39
162 Labda-8(17),12,14-triene, 12E-9-a- 3 115; 1-H4 [diagram] 2-[4.4.0]-3=CH2-2-R-1,7,7-Me Rice (Oryza sativa) EC 4.2.3.99
163 Sesquithujene, 7-epi- 3 c1-6,7*H6-2,3-H4 [diagram] 2-[3.1.0]-2-ene-5-R-2-Me Zea mays EC 4.2.3.101
164 Sesquithujene 3 c1-6,7*H6-2,3-H4 [diagram] 2-[3.1.0]-2-ene-5-R-2-Me Zea mays AAS88574, EC 4.2.3.102
165 Isokaurene, ent- 4 ent-107; 3-7',7*4,3-H1 [diagram] 4-[11.2.1.01,10,04,9]-14-ene-5,5,9-Me rice (Oryza sativa ) A4KAG7, A4KAG8, EC 4.2.3.103 4 gibberellins, platensimycin
166 Humulene, a- 3 1-11-10*H1-H3' [diagram] 1-[11]-1,4,8-ene-1,5,5,8-Me Zingiber zerumbet EC 4.2.3.104 zerumbone
167 Tricyclene 2 c1-6,7-3,2-H4 3-[2.2.1.02,6]-1,7,7-Me tomato (Solanum lycopersicum) G1JUH1, EC 4.2.3.105
168 Ocimene, (E)-b- 2 1-H4 0-[8]-1,3,6-ene many plants A4FVP2, EC 4.2.3.106
169 Carene, (+)-3- 2 c1-6,7-H5 [diagram] 2-[4.1.0]-3-ene-3,7,7-Me Picea abies (spruce), Pine AAM89254, AAO73863, EC 4.2.3.107
170 Tetraprenyl-b-curcumene 7 c1-6,7*H6-H5 1-[6]-1,4-ene-1-R-4-Me [diagram] Bacillus subtilis YtpB, EC 4.2.3.130 40
171 Sporulenol (Baciterpenol) 7 170; H+26,27-22,23-18,19-14,15-10,11-w [diagram] (4-[8.8.0.02,7.011,16]-6-CH2CH2CHMe-(1-[6])-1',4'-ene-5-ol-1,5,7,11,15,15,4'-Me Bacillus megaterium SqhC, BmeTC, EC 4.2.1.137 40
172 Bicyclic intermediate 6 128; H+3,2-7,6-11,10-w 2-[4.4.0]-3-ol-2-R-1,3,7,7-Me Bacillus megaterium SqhC, BmeTC 40
173 Onoceranoxide 6 172; H+22,23-18,19-14,15-O10 5-[13.8.0.03,12.06,11.016,21]-2-oxa-1,3,7,7,11,16,20,20-Me Bacillus megaterium BmeTC 40
174 Novel triterpene 6 172; H+22,23-18,19-14,15-H15' (2-[4.4.0])-2-CH2CH2-2'-(2-[4.4.0])-3-ol-3'=CH2-1,3,7,7,1',7',7'-Me Bacillus megaterium BmeTC 40
175 Achilleol A, 3-deoxy 6 128; H+3,2-7,6-H6' 1-[6]-1=CH2-2-R-3,3-Me Alicyclobacillus acidocaldarius mutant 40
176 Ambrein, (+)- 175; H+22,23-18,19-14,15-w (2-[4.4.0])-2-R-(1-[6])-3-ol-2'=CH2-1,3,7,7,6',6' Sperm whale BmeTC 40
177 Terpineol, (-)-a- 2 c1-6,7-w [diagram] 1-[6]-1-ene-4-C(OH)Me2-1-Me EC 4.2.3.111
ent-177 Terpineol, (+)-a- 2 c1-6,7-w [diagram] 1-[6]-1-ene-4-C(OH)Me2-1-Me EC 4.2.3.112
178 Terpinolene, (+)-a- (Mentha-1,4(8)-diene) 2 c1-6,7-H6 [diagram] 1-[6]-1-ene-4=CMe2-1-Me Abies grandis (grand fir) AAF61454, EC 4.2.3.113
179 Terpinene, a- 2 c1-6,7*H6-H1 [diagram] 1-[6]-1,3-ene-4-iPr-1-Me EC 4.2.3.115
180 Pinene, (-)-a- 2 c1-6,7-2,3-H4 [diagram] 2-[3.1.1]-2-ene-2,6,6-Me EC 4.2.3.119
ent-180 Pinene, (+)-a- 2 c1-6,7-2,3-H4 [diagram] 2-[3.1.1]-2-ene-2,6,6-Me EC 4.2.3.121
181 Pinene, (-)-b- 2 c1-6,7-2,3-H3' [diagram] 2-[3.1.1]-2=CH2-6,6-Me Abies grandis (grand fir) AAB71085, EC 4.2.3.119
ent-181 Pinene, (+)-b- 2 c1-6,7-2,3-H3' [diagram] 2-[3.1.1]-2=CH2-6,6-Me EC 4.2.3.122
182 Sesquiphellandrene, b- 3 c1-6,7*H1-H3' [diagram] 1-[6]-1-ene-3=CH2-6-R EC 4.2.3.123
183 Muurolene, (+)-a- 3 c1-10,11*H1-6,7-H8 [diagram] 2-[4.4.0]-2,7-ene-5-iPr-2,8-Me Coprinus cinereus (mushroom), Cucumis melo (melon) A8NE23 EC 4.2.3.125
184 Muurolene, (+)-g- 3 c1-10,11*H1-6,7-H7' [diagram] 2-[4.4.0]-2-ene-7=CH2-10-iPr-3-Me Coprinus cinereus (mushroom), Santalum album (sandalwood) A8NE23, B5A435, EC 4.2.3.126
185 Copaene, b- 3 c1-10,11*H1-6,7-2,3-H3' [diagram] 3-[4.4.0.02,7]-3=CH2-10-iPr-7-Me Coprinus cinereus A8NU13, EC 4.2.3.127
186 Cubebene, b- 3 c1-10,11*H1-6,7*H6-2,3-H3' [diagram] 3-[4.4.0.01,5]-4=CH2-7-iPr-10-Me Coprinus cinereus, Magnolia grandiflora A8NU13, B3TPQ6, EC 4.2.3.128
187 Sativene, (+)-b- 3 c1-10,11*H1-6,7-3,2*4,3-H3' [diagram] 3-[4.4.0.02,8]-7=CH2-3-iPr-6-Me Coprinopsis cinerea A8NU13, EC 4.2.3.129
188 Miltiradiene 4 107; 3-7',7-H6+1,2*3',3-H4 [diagram] 3-{8.4.0.02,7]-2(7),4-ene-5-iPr-1,11,11-Me Salvia miltiorrhiza, Rosmarinus officinalis G9MAN7 EC 4.2.3.131 tanshinones
189 Abieta-8(14),13(15)diene (neoabietadiene) 4 107; 3-7',7-H7'+1,2*3',3-H2 [diagram] 3-{8.4.0.02,7]-4-ene-5=CMe2-10,14,14-Me Abies grandis (grand fir) Q38710 EC 4.2.3.132
190 Copaene, a- 3 c1-10,11*H1-6,7-2,3-H4 [diagram] 3-[4.4.0.02,7]-3-ene-10-iPr-7-Me Helianthus annuus (sunflower) Q4U3F6, EC 4.2.3.133
191 Isocomene, a- 3 1-11,10-2,3*1,2-6,7*H2*7,6*H10*12,11-H1 [diagram] 3-{6.3.0.01,5]-6-ene-2,5,6,8-Me Matricaria chamomilla (chamomile) I6R4V5 EC 4.2.3.136 58
192 Valerena-4,10-diene 3 1-11,10-2,3*H2*10,11-H1; H+7,6-2,10-1,11*1,2-H3 2-[4.3.0]-1(9)-ene-2-CH=CMe2-5,9-Me Valeriana officinalis (valerian) EC 4.2.3.139 41
193 Tamariscene 3 1-11,10-2,3*H2*10,11-H1; H+7,6-10,2*H10-1,11-H12 3-[5.3.0.01,3]-2-C(=CH2)Me-4,8-Me Frullania tamarisci (liverwort) 41
194 Tamariscol 3 1-11,10-2,3*H2*10,11-H1; H+7,6-10,2-w 2-[4.3.0]-2-ol-2-CH=CMe2-3,7-Me Frullania tamarisci (liverwort) 41
195 Pacifigorgiol 3 1-11,10-2,3*H2*10,11-H1; H+7,6-2,10-1,11*1,2-H3 2-[4.3.0]-1-ol-2-CH=CMe2-3,7-Me Pacifigorgia cf. adamsii (gorgonian sponge) 41
196 Labda-7,13-diene-15-ol, (13E)- 4 H+14,15-10,11-6,7-H8; 1-w [diagram] 2-[4.4.0]-3-ene-2-R-1,3,7,7-Me Selaginella moellendorffii G1DGI7 bifunctional, EC 3.1.7.10
197 Labda-13-en-15-yl OPP, (13E)-8a-hydroxy (copal-8-ol PP) 4 H+14,15-10,11-6,7-w [diagram] 2-[4.4.0]-3-ol-2-R-1,3,7,7-Me Cistus creticus, Nicotiana tabacum (tobacco) E2IHE0, G3CCC0, EC 4.2.1.133
198 Abienol, cis- 4 197; 1-H4 [diagram] 2-[4.4.0]-3-ol-2-R-1,3,7,7-Me Abies balsamea (balsam fir), Nicotiana tabacum (tobacco) H8ZM73 bifunctional, EC 4.2.3.140
199 Sclareol 4 197; 3-w [diagram] 2-[4.4.0]-3-ol-2-R-1,3,7,7-Me Salvia sclarea (clary sage) AET21246, EC 4.2.3.141
200 Zingiberene, 7-epi 3 c1-6,7*H1-H4 (or *H5-H4?) [diagram] 1-[6]-1,3-ene-5-R-2-Me Solanum habrochaites EC 4.2.3.142
201 Kunzeol 3 1,10,11*H1-w [diagram] 1-[10]-1-ol-2,6-ene-10-iPr-3,7-Me Thapsia garganica K4LMW2, EC 4.2.3.143 thapsigargin
202 Geranyllinalool 4 3-w [diagram] 0-[16]-3-ol-1,6,10,14-ene-3,7,11,15-Me Arabidopsis thaliana Q93YV0 EC 4.2.3.144
203 Ophiobolin F 5 1-11,10-14,15*H8,6-2,3-w [diagram] 3-[9.3.0.03,7]-8-en-4-ol-12-R-1,4,8-Me Aspergillus clavatus A1C8C3, EC 4.2.3.145
204 Pimara-8(14),15-diene 4 107; 3-7',7-H7' [diagram] 3-[8.4.0.02,7]-6-ene-5-vinyl-1,5,11,11-Me Pinus banksiana (jack pine) and Pinus contorta (lodgepole pine) M4HY08, M4HYC8, EC 4.2.3.147
205 Cembrene C 4 1-14,15-H14 [diagram] 1-[14]-1,5,9-ene-12=CMe2-1,5,9-Me Streptomyces sp. SANK 60404 M1V9Q0, EC 4.2.3.148
206 Cembrene A, (R)- 4 1-14,15-H16 [diagram] 1-[14]-1,5,9-ene-12-C(=CH2)Me-1,5,9-Me Streptomyces sp. SANK 60404 M1V9Q0, EC 4.2.3.150
207 Pentamethylcyclo-pentadecatrienol 4 1-15,14-w [diagram] 1-[15]-3,7,11-en-1-ol-2,2,4,8,12-Me Streptomyces sp. SANK 60404 M1VDX3, EC 4.2.3.151
208 Macrocarpene, (-)-(S)-b- 3 41; H+10,11-7',7-H8 (1[6])-(1[6])-1,3'-ene-5,5,4'-Me Cupressus macrocarpa (Monterey cypress), Zea mays (maize) AAS88576 42, 50
209 Sesterfisherol 5 1-15,14-18,19*H12,10-6,7*H6*H10,12-2,3*H2*H12-w (?) 4-[9.7.0.03,7.013,17]-2-en-1-ol-16-iPr-2,6,10,13-Me Neosartorya fischeri NfTS2 44
210 Quiannulatene 5 1-15,14-18,19*H12,10-6,7*H6*H10,12-2,3-11,10*12,11*4,3-H2 5-[9.7.0.03,10.06.10.013,17]-1-ene-14-iPr-2,3,7,17-Me Aspergillus stellatus BAX76657 45
211 Sesquithuriferol 3 c1-6,7*H6-10,11-2,3*11,2-w 3-[5.3.0.01,4]-5-ol-4,6,6,10-Me 48
212 Cedrene (funebrene), (+)-b- 3 c1-6,7*H6-10,11-2,3-H4 3-[5.3.1.01,5]-8=CH2-2,6,6,8-Me
213 Zizaene (khusene) 3 c1-6,7*H6-10,11-3,2*4,3*12,11-H11' 3-[6.2.1.01,5]-6=CH2-2,7,7-Me
214 Prezizaene 3 c1-6,7*H6-10,11-3,2*4,3-H3' 3-[6.2.1.01,5]-7=CH2-2,6,6-Me
215 Prezizaene, (+)-2-epi 3 c1-6,7*H6-10,11-3,2*4,3-H3' 3-[5.2.2.01,5]-8-ene-2,6,6,8-Me 3m02 49
216 Duprezianene, a- 3 c1-6,7*H6-10,11-2,3*11,2*4,3-H1 3-[5.3.0.01,4]-5-ol-4,6,6,10-Me 49
217 Chamipinene, (-)-a- 2 c1-6,7-H6+10,11-6,7-2,3-H2 3-[5.3.1.01,6]-8-ene-2,2,6,8-Me Cupressus macrocarpa (Monterey cypress) 39, 50
218 Cumacrene (Dunniene) 3 c1-6,7-10,11-H12 (1-[6])-(1-[4])-3-ene-2'-C(=CH2)Me-4,1'-Me Cupressus macrocarpa (Monterey cypress) 39, 50
219 Grandisol 2 H+2,3-6,7-H8 1-[4]-1-CH2OH-2-C(=CH2)Me-1-Me
220 Fragranol 2 H+2,3-6,7-H8 1-[4]-1-CH2OH-2-C(=CH2)Me-1-Me
221 Widdra-2,4(14)-diene 3 c1-6,7-H6+10,11-6,7*5,6*H1-H3' 2-[5.4.0]-2-ene-4=CH2-7,11,11-Me
222 Chamigrene, Iso- 3 c1-6,7-H6+10,11-7,6*8,7-H7' spiro[5.5]-2-ene-7=CH2-3,8,8-Me 39
223 Isobazzanene 3 c1-6,7-H6+10,11-7,6*7',7-H8 (1-[6])-(1-[5])-3,1'-ene-1,4,5,5-Me Bazzania angustifolia 39, 63
224 Microbiotene, a- 3 c1-6,7-H6+10,11-7,6-2,3-H4 (2-[3.1.0])-5-(1-[5])-2-ene-2,1',2',2'-Me 39
225 Thalianol 6 129; H+O2,2-7,6-11,10-14,15*H14*10',10-H11 [diagram] 3-[7.4.0.02,6]-2(6)-ene-11-ol-5-R-1,5,10,10-Me Arabidopsis thaliana EC 5.4.99.31 51
226 Arabidiol 6 129; H+O2,2-7,6-11,10-14,15-w [diagram] 3-[7.4.0.02,6]-11-ol-5-R-1,6,10,10-Me Arabidopsis thaliana Q9FR95, EC 5.4.99.124 52
227 Marneral 6 129; H+O2,2-7,6-11,10*H11*6',6*H7*2,3-HO3 [diagram] 1-[6]-1=CMe2-2-CH2CH2CHO-3-R-3,4-Me Arabidopsis thaliana Q9FJV8, EC 5.4.99.53 53
228 Camelliol C 6 129; H+O2,2-7,6-H5 [diagram] 1-[6]-3-en-1-ol-5-R-4,6,6-Me Arabidopsis thaliana P0C8Y0, EC 5.4.99.38 54
229 Prosta-17(20),24-dien-3b-ol, (17Z)- 6 129; H+O2,2-7,6-11,10-15,14-18,19-H18 [diagram] 4-{8.7.0.02,7.011,15]-5-ol-1(10)-ene-14=R-2,6,6,10,11-Me EC 5.4.99.32
230 Cucurbitadienol 6 129; H+O2,2-7,6-11,10-15,14-18,19*H18*H14*15',15*10',10*H11*6',6*H7-H8 [diagram] 4-{8.7.0.02,7.011,15]-7-en-5-ol-14-R-1,6,6,11,15-Me EC 5.4.99.33
231 Parkeol 6 129; H+O2,2-7,6-11,10-15,14-18,19*H18*H14*15',15*10',10*H11-H12 [diagram] 4-{8.7.0.02,7.011,15]-1(17)-en-5-ol-14-R-2,6,6,11,15-Me EC 5.4.99.47 33
232 Germanicol 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22-H18 [diagram] 5-{12.8.0.02,11.05,10.015,20]-15-en-7-ol-1,2,6,6,10,17,17,20-Me EC 5.4.99.34
233 Amyrin, d- 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22*H18-H14 [diagram] 5-{12.8.0.02,11.05,10.015,20]-14-en-7-ol-1,2,6,6,10,17,17,20-Me EC 5.4.99.55
234 Amyrin, a- 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22*24,23*H22*H18*H14-H13 [diagram] 5-{12.8.0.02,11.05,10.015,20]-13-en-7-ol-1,2,6,6,10,16,17,20-Me EC 5.4.99.55
235 Amyrin, a-seco- 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22*24,23*H22*H18*H14*15,10-H9 [diagram] (2-[4.4.0])-7-CH2CH2-2'-(2-[4.4.0])-8,2'-en-3-ol-2,2,6,8,3',6',9',10'-Me EC 5.4.99.52
236 Dammarenediol II 6 129; H+O2,2-7,6-11,10-15,14-18,19-w [diagram] 4-{8.7.0.02,7.011,15]-5-ol-14-R-2,6,6,10,11-Me EC 4.2.1.125
237 Tirucalla-7,24-dien-3b-ol 6 129; H+O2,2-7,6-11,10-15,14-18,19*H18*H14*15',15*10',10-H9 [diagram] 4-{8.7.0.02,7.011,15]-9-en-5-ol-14-R-2,6,6,11,15-Me EC 5.4.99.56
238 Baccharis oxide 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18*H14*15',15*10',10*H11*6',6-O3 [diagram] 5-{14.2.1.01,14.02,11.05,10]-19-oxa-7-R-2,5,7,10,15,15-Me EC 5.4.99.51
239 Shionone 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18*H14*15',15*10',10*H11*6',6*H7*1,2*H3-HO3 [diagram] 4-{8.7.0.02,7.011,16]-5-one-14-R-1,6,7,11,14,16-Me EC 5.4.99.46
240 Baruol 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18*H14*15',15*10',10*H11*6',6*H7-H8 [diagram] 4-{8.7.0.02,7.011,16]-7-en-5-ol-14-R-1,6,6,11,14,16-Me Arabidopsis thaliana NP_193272, EC 5.4.99.57
241 Lupeol 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23-H24 [diagram] 5-{11.8.0.02,10.05,9.014,19]-17-ol-8-C(=CH2)Me-1,2,5,14,18,18-Me Arabidopsis thaliana Q9C5M3, EC 5.4.99.41
242 Lupan-3b,20-diol 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23-w [diagram] 5-{11.8.0.02,10.05,9.014,19]-17-ol-8-C(OH)Me2-1,2,5,14,18,18-Me Arabidopsis thaliana EC 4.2.1.128
243 Amyrin, b- 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22*H18*H14-H13 [diagram] 5-{12.8.0.02,11.05,10.015,20]-13-en-7-ol-1,2,6,6,10,17,17,20-Me EC 5.4.99.39
244 Amyrin, b-seco- 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22*H18*H14*15,10-H9 [diagram] (2-[4.4.0])-7-CH2CH2-2'-(2-[4.4.0])-8,2'-en-3-ol-2,2,6,8,3',6',9',9'-Me EC 5.4.99.54
245 Achilleol B 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22*H18*H14*15,10*11,6-H6' [diagram] (2-[4.4.0])-2-CH2CH2CH=CMeCH2CH2-(1-[6])-2-en-3'-ol-6'=CH2-3,6,9,9,2',2'-Me EC 5.4.99.48
246 Taraxerol 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22*H18*H14*15',15-H16 [diagram] 5-{12.8.0.02,11.05,10.015,20]-1(22)-en-7-ol-2,6,6,10,14,17,17,20-Me EC 5.4.99.35
247 Isomultiflorenol 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22*H18*H14*15',15*10',10-H11 [diagram] 5-{12.8.0.02,11.05,10.015,20]-2(11)-en-7-ol-1,6,6,10,14,17,17,20-Me EC 5.4.99.36
248 Glutinol 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22*H18*H14*15',15*10',10*H11*6',6*H7-H8 [diagram] 5-{12.8.0.02,11.05,10.015,20]-4-en-7-ol-1,6,6,11,14,17,17,20-Me EC 5.4.99.49
249 Friedelin 6 129; H+O2,2-7,6-11,10-15,14-18,19*17,18-22,23*21,22*H18*H14*15',15*10',10*H11*6',6*H7*1,2*H3-HO3 [diagram] 5-{12.8.0.02,11.05,10.015,20]-7-one-1,5,6,11,14,17,17,20-Me EC 5.4.99.50
250 Tetrahymanol 6 128; H+3,2-7,6-11,10-15,14-19,18-23,22-w 5-[12.8.0.02,11.05,10.015,20]-7-ol-1,2,6,6,10,15,19,19-Me EC 4.2.1.123
251 Hopan-22-ol (diplopterol) 6 128; H+3,2-7,6-11,10-15,14-19,18-22,23-w 5-[11.8.0.02,10.05,9.014.19]-6-C(OH)Me2-1,2,9,14,18,18-Me EC 4.2.1.129
252 Dammara-20,24-diene 6 128; H+3,2-7,6-11,10-15,14-18,19-H19' [diagram] 4-{8.7.0.02,7.011,15]-14-R-2,6,6,10,11-Me EC 5.4.99.37
253 Drimenol 3 H+10,11-6,7-2,3-H4 2-[4.4.0]-3-ene-2-CH2OH-1,3,7,7-Me Persicaria hydropiper EC 3.1.7.7
254 Cyatha-3,12,-diene, (-)- 4 c1-7,6-10,11*9,10-14,15*H14-H10 3-[7.5.0.02,6]-2,11-ene-3-iPr-6,9,12-Me Cyathus africatus , Hericium erinaceum CyaTC, EriG 55
255 Neoverrucosan-5b-ol 4 c1-7,6-10,11*9,10-14,15*H5-3,2-w 4-[7.5.0.02,6.012,14]-11-ol-3-iPr-6,9,12-Me Saprospira grandis SapTC1 55
256 Verrucosan-5b-ol 4 c1-7,6-10,11*9,10-14,15*H5-3,2*4,5-w 4-[7.5.0.02,6.011,13]-14-ol-3-iPr-6,9,13-Me Chloroflexus sp. ChlTC5 55
257 Lydicene 4 c1-7,6-10,11*9,10-14,15*13,14*H10-H6 3-[8.5.0.02,7]-1,12-ene-4,4,7,10,13-Me Streptomyces lydicus, StlTC 55
258 Axinyssene 4 c1-6,7-H7' 1-[6]-3-ene-1-R-4-Me Cystobacter violaceus CysTC2 55
259 Asterisca-2(9),6-diene 3 1-11,10*H9-2,3-6,7*6,3*H2-H9 2-[6.3.0]-1(8),3-ene-3,7,10,10-Me Dictyostelium discoideum DdTPS2 56
260 Protoilludene,D7- 3 1-11,10*H9-2,3-6,7-H8 3-[6.3.0.02,5]-6-ene-2,6,10,10-Me Dictyostelium discoideum DdTPS6 56
261 Maaliene, b- 3 1-10,11-H1; H+6,7-2,3-H2 3-[5.4.0.02,4]-1(11)-ene-3,3,7,11-Me 57
262 Aristolene 3 1-10,11-H1; H+6,7-2,3*H2*7',7-H8 3-[5.4.0.02,4]-6-ene-1,3,3,11-Me 57
263 Calarene 3 1-10,11-H1; H+6,7-2,3*H2*7',7-H6 3-[5.4.0.02,4]-7-ene-1,3,3,11-Me 57
264 Chrysanthemyl OPP 1+1 1-3,2-H1 1-[3]-1-CH2OPP-2-R-3,3-Me Sagebrush, Chrysanthemum EC 2.5.1.67 61 Pyrethrins
265 Maconellyl OPP 1+1 1-2,3-2,3-H2 1-[4]-1-CH2OPP-3=CMe2-2,2-Me 61
266 Planococcyl OPP 1+1 1-2,3-2,3-H4 1-[4]-1-CH2OPP-3-C(=CH2)Me-2,2-Me 61
267 Lavandulyl OPP 1+1 1-2,3-4 0-[6]-4-ene-1-OPP-2-C(=CH2)Me-5-Me Lavandula lanata 5hc7 61
268 Ishwarane 3 26; H+6,7-2,3*H2*7',7-12,11-H9 4-[7.2.1.02,11.04,9]-1,4,5-Me Aristolochia indica 62
269 Presqualene OPP 3+3 1-2,3-H1 1-[3]-1-CH2OPP-2-R-3-R'-2-Me
270 Dehydrosqualene, cis 3+3 1-2,3-H1; 1*1,3*2,1-H1 0-[24]-2,6,10,12,14,18,22-ene-2,6,10,15,19,23-Me Staphylococcus aureus KXA36522, EC 2.5.1.96 2zco 61
271 Helifolene 3 c1-6,7*H6-10,11-3,2-H1 3-[5.2.2.01,5]-8-ene-2,6,6,7-Me 61
272 Acoradiene, b- 3 c1-6,7*H6-10,11-H12 2-spiro[4.5]-7-ene-1-C(=CH2)Me-4,8-Me 61
273 Helminthogermacrene, (-)- 3 c1-10,11-H12 1-[10]-1,5-ene-8-C(=CH2)Me-1,5-Me 61
274 Hinesene 3 26; H+6,7-2,3*H2*8,7-H6 2-spiro[4.5]-6-ene-2-C(=CH2)Me-6,10-Me 61
275 Spirolepechinene 3 26; H+6,7-2,3*H2*6,7-H7' 2-spiro[4.5]-6=CH2-9-C(=CH2)Me-1-Me 61
276 Dolabella-3,7,18-triene 4 1-11,10-14,15-H16 2-[9.3.0]-3,7-ene-12-C(=CH2)Me-1,4,8-Me 61
277 Araneosene, b- 4 1-11,10-14,15-H14 2-[9.3.0]-3,7-ene-12=CMe2-1,4,8-Me Sordaria araneosa 61
278 Santolina alcohol 1+1 1-3,2-H1; 1*2,3-w 0-[6]-4-en-2-ol-3-vinyl-2,5-Me Achillea ageratum
279 Thujene, a- 2 c1-6,7*H6-2,3-H4 2-[3.1.0]-2-ene-5-iPr-2-Me Satureja hortensis (summer savory)
280 Artemisiatriene 2 1-3,2-H1; 1*2,1-H4 0-[7]-1,3,6-ene-2,5,5-Me Artemisia vulgaris (mugwort)
281 Yomogi alcohol 2 1-3,2-H1; 1*2,3-w 0-[7]-3,6-en-2-ol-2,5,5-Me
282 Artemisia alcohol 2 1-3,2-H1; 1*2,1-w 0-[7]-1,5-en-4-ol-3,3,6-Me
283 Terpinen-4-ol 2 c1-6,7*H6-w 1-[6]-3-en-1-ol-1-iPr-4-Me Melaleuca alternifolia (tea-tree), Juniperus communis (juniper)
284 Piperitol 2 c1-6,7*H1-w 1-[6]-2-en-1-ol-6-iPr-3-Me cumin
285 Campholenol, a- 2 c1-6,7-3,2*3,4-w 1-[5]--1-ene-4-CH2CH2OH-1,5,5-Me
286 Dihydrocarveol, (-)- (p-Menth-8-en-2-ol) 2 c1-6,7-H8+3,2-w 1-[6]-1-ol-3-C(=CH2)Me-6-Me Mentha sp. (Mint), Piper longum (long pepper)
287 Helmiscapene, b- 3 1-10,11-H12; H+6,7-2,3-H3' 2-[4.4.0]-2=CH2-9-C(=CH2)Me-6-Me
288 Isocyclobazzanene 3 c1-6,7-H6+10,11-7,6*7',7-H8+2,3-8,7-H8 3-[5.2.2.02,6]-2(6)-ene-1,3,3,7-Me Bazzania angustifolia 63
289 Brasila-5,10-diene 3 2-[4.3.0]-1-ene-2-C(=CH2)Me-4,4,7-Me Conocephalum conicum
290 Conocephalenol 3 2-[4.3.0]-1-ene-2-C(OH)Me2-4,4,7-Me Conocephalum conicum
291 Opposita-4(15),7-diene 3 30; H+6,7-2,1*9,10-H11 2-[4.3.0]-2=CH2-9-CH=CMe2-6-Me 64
292 Cycloaxene, 4(15)- 3 30; H+6,7-2,1-H9 3-[4.4.0.02,4]-9-ene-3-iPr-6,10-Me 64
293 Silphin-1-ene 3 1-11,10-2,3*1,2-6,7*H2*7,6-H5 3-[6.3.0.01,5]-2-ene-5,7,7,11-Me
294 Clovene, (-)- 3 54; H+6,7-3',3*10,2-H1 3-[6.3.1.01,5]-2-ene-4,4,8-Me
295 Cyclomyltaylane 3 c1-6,7-H6+10,11-6,7-2,3*1,2*4,3-H4 4-[6.2.1.01,6.07,9]-2,2,6,9-Me Bazzania tridens (a liverwort)
296 Pinguisene, (+)-a- 3 3-11,10-6,7*H10*12,11*H6*12,10*11',11,3',3-H4 (?) 2-[4.3.0]-3-ene-3-vinyl-1,2,6,7-Me
297 Capnell-9(12)-ene 3 1-11,10*H8,6-2,3-H3' 3-[6.3.0.02,6]-3=CH2-8,11,11-Me
298 Ylangene, a- 3 1-10,11*H1-6,7-2,3-H4 3-[4.4.0.02,7]-3-ene-10-iPr-3,7-Me
299 Cyclosativene, (+)- 3 c1-10,11*H1-6,7-3,2-H4 4-[4.4.0.02,4.03,7}-8-iPr-1,2-Me
300 Bourbonene, (-)-b- 3 1-10,11*H1-7,6-2,3-H3' 3-[5.3.0.02,6]-3=CH2-10-iPr-7-Me
301 Isodauca-4,7(14)-diene 3 1-10,11*H1-7,6*H1-H10; H+2,3-H3' 2-[5.3.0]-7-ene-5=CH2-8-iPr-1-Me
302 Isoledene, (-)- 3 1-10,11-H1; H+7,6-2,3*H2-H6 (?) 3-[5.3.0.02,4]-1(7)-ene-3,3,7,11-Me
303 Longicyclene, (+)- 3 1-11,10*H1-6,7-3,2-H4 4-[5.4.0.02,9.08,10]-3,3,7,8-Me
304 Modhephene 3 1-11,10-2,3*1,2-6,7*H2*7,6*H10*6,2*4,3-H1 3-[3.3.3.01.5]-2-ene-2,4,4,8-Me
305 Cameroonan-7-ol 3 1-11,10-2,3*1,2-6,7*H2*9,10-w 3-[6.3.0.01,5]-2-ol-3,3,5,9-Me 66
306 Terrecyclene, a- 3 1-11,10-2,3*H2-6,7*H6*1,2*H3-H4 or 1-11,10-2,3*1,2-6,7*H2*7,6*10,2*1,3-H4 3-[4.3.2.01,5]-2-ene-2,9,11,11-Me 66
307 Prenopsan-8-ol 3 1-11,10-2,3*1,2-6,7*H2*9,10*6,2-w 3-[5.4.0.04,8]-8-ol-4,6,6,11-Me 66
308 Nopsan-4-ol 3 1-11,10-2,3*1,2-6,7*H2*9,10*6,2*4,3-w 3-[4.3.2.01,5]-2-ol-2,4,4,7-Me 66
309 Italicene 3 c1-11,10-6,7*H6-H1 (?) 3-[5.4.0.01,5]-8-ene-2,6,6,9-Me
310 Asterisca-3(15),6-diene 3 1-11,10*H9-2,3-H3' (?) 2-[6.3.0]-3-ene-7=CH2-3,10,10-Me
311 Panasinsene, b- 3 1-11,10-2,3-H2; H+6,7-2,3-H3' 3-[5.4.0.01,4]-11=CH2-3,3,7-Me
312 Isolongifolene, (-)- 3 3-[6.2.1.01,6]-5-ene-2,2,6,6-Me
313 Petasitene 3 3-[5.2.1.02,6]-4-ene-5-iPr-2,6-Me
314 Cyperene, a- 3 1-10,11-6,7*H6-2,3-H2 3-[5.3.1.01,5]-4-ene-4,10,11,11-Me
315 Seychellene 3 3-[5.2.1.03,8]-2=CH2-3,6,8-Me
316 Cycloseychellene 3 4-[5.2.1.02,10.03,8]-2,3,6,8-Me
317 Cascarilladiene (Eudesma-5,7-diene) 3 1-10,11*H1-H10; H+6,7-2,3*H2-H9 2-[4.4.0]-1,3-ene-3-iPr-6,10-Me Croton eluteria, Solidago canadensis (Canadian golden rod) Q66NG3
318 Isosativene, (-)- 3 3-[5.2.1.03,8]-2=CH2-6-iPr-3-Me
319 Tritomarene (kelsoene), (+)- 3 1-11,10-7,6-2,3*H1*10,11-H12 3-[5.3.0.02,5]-6-CMe2-2,8-Me Tritomaria quinquedentata (a liverwort), Cymbastela hooperi (a sponge) 67
320 Spirovetiva-1(10),7(11)-diene 3 145; H+6,7-2,3*H2*8,7-H6 2-spiro[4.5]-6-ene-2=CMe2-6,10-Me
321 Isobarbatene 3 c1-6,7-H6+10,11-7,6*7',7*12,11-2,3*11,2*4,3*11',11-H10 3-[6.2.1.02,6]-5-ene-1,2,6,6-Me Meum athamanticum 68
322 Chenopodene 3 c1-6,7*5,6-2,3-H4 2-[4.1.0]-2-ene-5-R-2,5-Me Marchantia chenopoda (a liverwort) 69
323 Sesquifenchene 3 c1-6,7-2,3*1,2*4,3-H3' 2-[2.2.1]-2=CH2-7-R-7-Me Valeriana waalichi
324 Fenchene, (-)- 2 c1-6,7-2,3*1,2*4,3-H3' 2-[2.2.1]-2=CH2-7,7-Me Valeriana officinalis (valerian)
325 Sesquisabinene 3 c1-6,7*H6-2,3-H3' 2-[3.1.0]-2=CH2-5-R Piper nigrum (pepper)
326 Gorgonene, b- 3 1-10,11-H1; H+6,7-2,3-H3'; H+10,11-H12 2-[4.4.0]-2=CH2-10-C(=CH2)Me-6-Me Pseudopterogeorgia americana
327 Cyclofarnesa-5(14),8,10-triene 3 62; H+10,11-6,7-H7' 1-[6]-1=CH2-2-R-3,3-Me
328 Aromadendrene, (+)- 3 29; H+3,2-6,7-H7' 3-[6.3.0.02,4]-7=CH2-3,3,11-Me allspice, Eucalyptus globulus
329 Erythrodiene 3 1-10,11*H1-H3'; H+6,7-2,1*H2*6,7-H7' 2-spiro[4,5]-1,6=CH2-9-iPr Eryrhropodium caribaeorum 70
330 Himachalene, a- 3 c1-11,10*H1-6,7-H7' 2-[5.4.0]-8-ene-2=CH2-6,6,9-Me Cedrus deodara (Himalayan cedar)
331 Neoclovene, (-)-a- 3 1-11,10-3,2-7,6*H2*8,7-H6 or
1-11,10-2,3-H2; H+6,7-2,3*10,2*8,7-H6
3-[5.2.2.02,7]-5-ene-2,6,9,9-Me acidic rearrangement of caryophyllene - not natural?
332 Rotundene 3 26; H+3,2-6,7-12,11-H12 3-[6.2.2.02,6]-9-ene-1,5,9-Me Cyperus scariosus
333 Striatene 3 62; H+10,11-6,7*H6*12,11*H7-H8 1-[6]-1-ene-3-R-2,3,4-Me Ptychanthus striatus (liverwort)
334 Carota-5,8-diene (Dauca-5,8-diene) 3 c17,6-10,11*H9-H8+3,2-H1 2-[5.3.0]-2,9-ene-8-iPr-1,4-Me
335 Nardosina-1(10),11-diene 3 2-[4.4.0]-1-ene-7-C(=CH2)Me-5,6-Me Nardostachys chinensis
336 Harzianone, deoxy 4 1-14,15-10,11*H10-2,3-6,7-H6 4-[9.3.1.01,9.05,8]-4-ene-4,8,14,15,15-Me Trichoderma sp. 34 73
337 Preterpestacin I 5 1-15,14-18,19*H12,10-w 2-[13.3.0]-3,8,12-en-5-ol-18-iPr-4,8,12,15-Me Arthrinium sp. SF1744, Bipolaris maydis 74 terpestacin
338 a-Ionylidene-ethane 3 1-H4; +H1,2-H5; +H10,11-6,7-H8 1-[6]-1-ene-3-R-2,4,4-Me Botrytis cinerea BcABA3 75 Abscisic acid in fungi
339 Pupukeanol (presumed) 3 c1-6,7*H1-10,11*H7-H8; +H1,2-8,7*9,8-w 3-[4.3.1.03,7]-1,6-Me-4-iPr-10-ol Phyllidia varicosa, Hymeniacidon sp. 76
340 Neopupukeanol (presumed) 3 c1-6,7*H1-10,11*H7-H8; +H1,2-8,7*5,6-w 3-[4.3.1.03,7]-3,6-Me-9-iPr-10-ol Ciocalypta sp. 76
341 Abeopupukeanol (presumed) 3 c1-6,7*H1-10,11*H7-H8; +H1,2-8,7*9,8*2,3-w 3-[4.4.0.02,8]-1,5-Me-9-iPr-5-ol Phyllidia coelestis Bergh 76
342 3
; a- 2 EC

References

1. Nat. Prod. Rep., 2016, 33, 87 10.1039/c5np00102a
2. ACS Chem. Biol. 2017, 12, 1621 10.1021/acschembio.7b00154
3. FEBS Lett. 2008, 582 (5), 565 10.1016/j.febslet.2008.01.020
4. PNAS 2011, 108 (33), 13498 10.1073/pnas.1106919108
5. J. Biol. Chem. 2002, 277 (40), 37098 10.1074/jbc.M206382200
6. Nat. Prod. Rep., 2014, 31, 1449 10.1039/c4np00075g
7. J. Biol. Chem. 1998, 273 (24), 14891 10.1074/jbc.273.24.14891
8. J. Am. Chem. Soc. 2009, 131 (24), 8360 10.1021/ja9021649
9. Tetrahedron Lett., 1987, 28, 4887 10.1016/S0040-4039(00)96652-8
10. Angew Chem Int Ed., 2017, 56 (10), 2776-9 10.1002/anie.201612439
11. J. Biol. Chem. 2012, 287, 6840-50 10.1074/jbc.M111.337592
12. Nature 2010, 469, 116–120 10.1038/nature09628
13. Nature Chem. Biol. 2011, 7, 431–433 10.1038/nchembio.578
14. PLoS One, 2012, 7, e35450 10.1371/journal.pone.0035450
15. Biosci. Biotechnol. Biochem., 2008, 72 (4), 1038 10.1271/bbb.70790
16. J. Am. Chem. Soc. 2001, 123, 5154 10.1021/ja015747j
17. J. Antibiot. 1976, 29 (2), 125 10.7164/antibiotics.29.125
18. Biosci. Biotech. Biochem., 2007, 71 (12), 3116 10.1271/bbb.70547
19. Sci. Rep., 2016, 6, no. 25202 10.1038/srep25202
20. J. Org. Chem., 2009, 74 (4), 1541 10.1021/jo802319e
21. ACS Chem. Biol., 2016, 11 (4), 889 10.1021/acschembio.5b00960
22. Proc. Natl. Acad. Sci. U. S. A., 2007, 104, 3084 10.1073/pnas.0608426104
23. Org. Lett., 2009, 11 (14), 3044 10.1021/ol901063s
24. Science, 1997, 277, 1811 10.1126/science.277.5333.1811
25. Structure, 2011, 19 (12), 1876 10.1016/j.str.2011.09.013
26. Biochemistry, 2015, 54 (48), 7142 10.1021/acs.biochem.5b01143
27. Angew. Chem. Int. Ed., 2014, 53, (29), 7652 10.1002/anie.201403648
28. Biochem. J., 2013, 451 (3) 417 10.1042/BJ20130041
29. Plant Cell, 2007, 19 (6), 1994 10.1105/tpc.106.047779
30. Proc. Natl. Acad. Sci., 2007, 104 (13), 5360 10.1073/pnas.0700915104
31. Acta Cryst. (2016). F72, 16 10.1107/S2053230X15023043
32. Biochemistry 2009, 48 (26), 6175 10.1021/bi900483b
33. Nature, 2004, 432 (7013), 118 10.1038/nature02993
34. Plant Physiology, 2004, 135 (4), 2098 10.1104/pp.104.045971
35. Plant J., 2004, 37 (1), 1 10.1046/j.1365-313X.2003.01926.x
36. ChemBioChem, 2913, 14 (3), 316 10.1002/cbic.201200651
37, Nat. Prod. Bioprospect., 2015, 5 (3), 167 10.1007/s13659-015-0065-3
38. J. Am. Chem. Soc. 2010, 132, 2998 10.1021/ja909251r
39. J. Am. Chem. Soc., 2014, 136 (6), 2450 10.1021/ja4106489 [Computation]
40. Angew. Chem. Int. Ed. 2015, 54, 2604 10.1002/anie.201407883 [Review]
41. J. Biol. Chem., 2013, 288 (5), 3163 10.1074/jbc.M112.415836 [Isotopic labelling]
42. J. Biol. Chem., 2008, 283 (5), 20779 10.1074/jbc.M802682200 [Gene expression + deuterium labelling]
43. J. Antibiot. 2017, 70, 632 10.1038/ja.2017.27 [Deuterium labelling]
44. J. Am. Chem. Soc., 2015, 137 (36), 11846 10.1021/jacs.5b08319 [Gene expression, 13C-labelling]
45. J. Am. Chem. Soc., 2016, 138 (31), 10011 10.1021/jacs.6b05799 [Gene expression + 13C labelling]
46. J. Antib. 2015, 68 (6), 385 10.1038/ja.2014.171; Proc. Natl Acad. Sci. 2015, 112 (3), 857 10.1073/pnas.1422108112 [Gene expression + structure determination]
47. ChemBioChem 2014, 15 (2), 213 10.1002/cbic.201300708 [Crystal structure]
48. J. Am. Chem. Soc., 2009, 131 (23), 7999 10.1021/ja9005332 [Computation]
49. ACS Chem. Biol., 2010, 5 (4), 377 10.1021/cb900295g [Crystal structure, products using cis farnesyl OPP]
50. Phytochem. 2005 66 (2), 249 1016/j.phytochem.2004.11.002 [Isolation, structure determination]
51. Science, 2008, 320 (5875), 543-7 10.1126/science.1154990
52. Org Lett., 2006, 8 (13), 2835-8 10.1021/ol060973p
53. Proc. Natl. Acad. Sci., 2011, 108 (38), 16116–16121 10.1073/pnas.1109273108
54. Org. Lett., 2007, 9 (25), 5223–5226 10.1021/ol702399g
55. Angew. Chem. Int. Ed., 2017, 56, 4749 10.1002/anie.201700565
56. Angew. Chem. Int. Ed., 2016, 55, 15420 10.1002/anie.201608971
57. Proc. Natl. Acad. Sci., 2016, 113 (43), 12132 10.1073/pnas.1610379113
58. Chem. Eur. J., 2013, 19, 13590 10.1002/chem.201301018 [Computation & Isotope labelling]
59. Angew. Chem. Int. Ed., 2016, 55, 13593 10.1002/anie.201608042[Isotope labelling]
60. ChemBioChem, 2016, 17, 146 10.1002/cbic.201500543 [Computation & Isotope labelling]
61. Chem. Rev., 2017, 117, 11570 10.1021/acs.chemrev.7b00287 [Review]
62. Tetrahedron, 1970, 26 (2), 615 10.1016/S0040-4020(01)97854-8 [Isolation]
63. Nat. Prod. Rep., 1985, 2, 147 10.1039/NP9850200147 [Review]
64. Phytochemistry 2000, 55, 141 10.1016/S0031-9422(00)00266-1 [Mechanism]
65. Phytochemistry, 1992,.31 (6), 2150 10.1016/0031-9422(92)80385-R
66. Eur. J. Org. Chem. 1998, 1205 10.1002/(SICI)1099-0690(199806)1998:6<1205::AID-EJOC1205>3.0.CO;2-K [Isolation & Structure]
67. Chem. Commun., 2001, 2154 10.1039/B101579F [Abs config. & synthesis]
68. Tetrahedron, 1978, 34 (1) 47 10.1016/0040-4020(78)88034-X [structure & mechanism]
69. Phytochem. 1994, 36 (1), 73 10.1016/S0031-9422(00)97015-8 [isolation & structure]
70. Tetrahedron Lett. 1993, 34 (21), 3371 10.1016/S0040-4039(00)79158-1 [isolation & structure]
71. Org. Biomol. Chem., 2017, 15, 2353 10.1039/C7OB00234C
72. ChemBioChem, 2017, 18 (23), 2317-2322 10.1002/cbic.201700434 [biosynthetic pathway]
73. ChemBioChem, 2017, 18 (23), 2358-2365 [isolation & isotopic labelling]
74. J. Org. Chem. 2018, 83 (13), 7042-7048 10.1021/acs.joc.7b03220
75. J. Am. Chem. Soc., 2018, 140 (39), 12392-12395 10.1021/jacs.8b08925 [enzyme study & isotopic labelling]
76. J. Phys. Chem. A, 2018, 122 (40), 8058-8061 10.1021/acs.jpca.8b07961 [mechanism computation]; J. Nat. Prod., 2013, 76 (11), 2158-2161 10.1021/np4007074 [isolation & biosynthetic proposal]